Methacrylic Acid
AKA “79-41-4, 2-methylprop-2-enoic acid, 2-Methylacrylic acid, Methylacrylic acid, 2-Propenoic acid, 2-methyl-, 2-Methylpropenoic acid, 2-Methyl-2-propenoic acid, alpha-Methylacrylic acid, 2-Methylenepropionic acid
Acid
Ingredient Facts
Methacrylic acid
AKA: 79-41-4, 2-methylprop-2-enoic acid, 2-Methylacrylic acid, Methylacrylic acid, 2-Propenoic acid, 2-methyl-, 2-Methylpropenoic acid, 2-Methyl-2-propenoic acid, Alpha-Methylacrylic acid, 2-Methylenepropionic acid
Acid · Film Forming · EWG: 6
Synthetic
Occlusive
Acid
Not Clean
Methacrylic acid, stabilized appears as a clear colorless liquid with a pungent odor. Corrosive to metals and tissue. Combustible. Flash point 170 °F. Melting point 61 °F. May polymerize if contaminated or heated. If polymerization takes place inside a closed container, the container may violently rupture. Less dense than water and is soluble in water. Vapors heavier than air. Used to make plastics.
Solubility greater than or equal to 100 mg/mL at 63 °F (NTP, 1992)
Formula
C4H6O2
Mol. Weight
86.09
CAS #
79-41-4
Form
Liquid
State
Methacrylic acid appears as a clear colorless liquid (or low-melting solid) with a pungent odor. Corrosive to metals and tissue. Flash point 170 °F. Melting point 61 °F. May polymerize exothermically
See origin →
Functions
Film Forming
Creates a physical seal on skin to lock moisture in and keep irritants out. The "slugging" ingredient — barrier protection.
Creates Protective Barrier
Wound Healing
Fights Bacteria
Traditional Use
Developed in the early 20th century as part of modern polymer chemistry; used in cosmetics since mid-century as a raw material for creating film-forming and thickening agents in skincare and haircare products.
Skin Types
all-skin-types
Best For
General
Pregnancy & Breastfeeding Safe
Caution
EWG
6
CIR
Safe as used
Pregnancy
Caution
CIR Safety Findings
Not a Sensitizer
medical-approval
all-shades-safe
Regulatory Status
USApermitted
EUrestricted
JAPANrestricted
CANADArestricted
Final Report on the Safety Assessment of 2-Methyl-5-Hydroxyethylaminophenol
Cosmetic Ingredient Review (CIR) Expert Panel
International Journal of Toxicology
Final Report on the Safety Assessment of Methacrylic Acid
Cosmetic Ingredient Review (CIR) Expert Panel
International Journal of Toxicology
2-Methyl-5-Hydroxyethylaminophenol
European Commission
EU Cosmetic Ingredient Database (CosIng)
C8-22 Alkyl Acrylates/Methacrylic Acid Crosspolymer
European Commission
EU Cosmetic Ingredient Database (CosIng)
Methacrylic Acid
European Commission
EU Cosmetic Ingredient Database (CosIng)
Methacrylic Acid/Styrene/VP Copolymer
European Commission
EU Cosmetic Ingredient Database (CosIng)
PEG/PPG-5/2 Methacrylate/Methacrylic Acid Crosspolymer
European Commission
EU Cosmetic Ingredient Database (CosIng)
2-Methyl-1-Phenyl-2-Propanol
Environmental Working Group (EWG)
EWG Skin Deep Cosmetics Database
2-Methyl-5-Hydroxyethylaminophenol
Environmental Working Group (EWG)
EWG Skin Deep Cosmetics Database
C8-22 Alkyl Acrylates/Methacrylic Acid Crosspolymer
Environmental Working Group (EWG)
EWG Skin Deep Cosmetics Database
Methacrylic Acid
Environmental Working Group (EWG)
EWG Skin Deep Cosmetics Database
2-Methyl-m-phenylenediamine
Health Canada
Health Canada Cosmetic Ingredient Hotlist
Methacrylic acid
Health Canada
Health Canada Cosmetic Ingredient Hotlist
Verified Jun 2026
Data: PubChem · CosIng · EWG · CIR